Uranyl-tri-bis(silyl)amide Alkali Metal Contact and Separated Ion Pair Complexes
نویسندگان
چکیده
منابع مشابه
Selective recognition of an alkali halide contact ion-pair.
For more than 30 years there has been an active and continued effort to develop synthetic receptors for anions and cations in organic solvents.1 We2 and others3 have shown that if both of the counterions in a target salt have localized charges then the consequent ion-pairing of the salt can dramatically lower receptor/ ion binding affinities and alter binding selectivities. One way to counter t...
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Phosphine is conformationally stable because of the high inversion energy barrier of the phosphorus atom, which allows the phosphorus atom to become a chiral center. Thus, enantiopure P-stereogenic 12-, 15-, 18-, and 21-membered aliphatic phosphines "diphosphacrowns" were synthesized from secondary P-stereogenic bisphosphine as a chiral building block. Their complexation behaviors with alkali m...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2018
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.8b00715